Volume 23, Issue 1, May 2016, Pages 124–133
Gianluca Intini1, Gabriella De Santis2, and Lorenzo Liberti3
1 T&A Technology and Environment, Bari, Italy
2 Technical University of Bari, Italy
3 Department of Civil Environmental Building Engineering and Chemistry, Technical University of Bari, Bari, Italy
Original language: English
Copyright © 2016 ISSR Journals. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Energy production by combustion of S-containing non-renewable fuels requires huge consumption of limestone for the necessary Flue Gas Desulfurization (FGD) treatment in order to meet stringent SO2 emission limits. FGD (wet, dry or semi-dry) is an expensive, energy intensive, process due to its overall poor efficiency and to the need of using finely micronized CaCO3. Wet FGD laboratory tests with dolomite slurry have shown that up to ≈ 50% higher performance and faster SO2 uptake occur if the mineral is micronized by high energy mill, yielding mechanochemical activation of the solid. Further benefits arise from the use of dolomite which consistently contains Mg carbonate.
Author Keywords: flue gas desulfurization, mechanochemical activation, limestone or dolomite micronization, SO2 emission.
Gianluca Intini1, Gabriella De Santis2, and Lorenzo Liberti3
1 T&A Technology and Environment, Bari, Italy
2 Technical University of Bari, Italy
3 Department of Civil Environmental Building Engineering and Chemistry, Technical University of Bari, Bari, Italy
Original language: English
Copyright © 2016 ISSR Journals. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
Energy production by combustion of S-containing non-renewable fuels requires huge consumption of limestone for the necessary Flue Gas Desulfurization (FGD) treatment in order to meet stringent SO2 emission limits. FGD (wet, dry or semi-dry) is an expensive, energy intensive, process due to its overall poor efficiency and to the need of using finely micronized CaCO3. Wet FGD laboratory tests with dolomite slurry have shown that up to ≈ 50% higher performance and faster SO2 uptake occur if the mineral is micronized by high energy mill, yielding mechanochemical activation of the solid. Further benefits arise from the use of dolomite which consistently contains Mg carbonate.
Author Keywords: flue gas desulfurization, mechanochemical activation, limestone or dolomite micronization, SO2 emission.
How to Cite this Article
Gianluca Intini, Gabriella De Santis, and Lorenzo Liberti, “FLUE GAS DESULFURIZATION BY MECHANOCHEMICALLY ACTIVATED DOLOMITE,” International Journal of Innovation and Scientific Research, vol. 23, no. 1, pp. 124–133, May 2016.